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Wednesday, January 18, 2023

Chemical reaction, type of reaction, chemical reaction in chemistry, 10 most important chemical reaction in chemistry,

  Chemical Reactions  

In chemistry there are many types of chemical reactions some reactions are in generally known as naming reactions. Some reactions are: - Wurtz reactions, Grignard reactions, Fitting reactions, Wurtz Fitting reactions, Williamson's synthesis, Kolbe's Electrolysis reactions, Friedel Craft Acylation reactions, Friedel Craft Alkylation reactions, Diazotization Reactions, Hoffmann's Bromide reactions, Carbylamine reactions, Riemer - Tiemann Reaction,  Finkelstein reaction, Clemmensen reduction, Esterification Reaction, Cannizzaro's Reactions, Elb's Reactions, Ullmann reactions, Étard's reactions, Sandmeyer reactions, Aldol Condensation reaction, Markownikoff's Rule, Antimarkownikoff's rule, Tollen's Reagent, Fehling solution, 

Wurtz Reactions- The reactions in which higher alkanes are prepared by heating of alkyl halides (RX) with sodium (Na) in the presence of dry ether is called Wurtz reactions.

Wurtz reaction

Grignard Reactions: - The reactions in which alkyl maghalide(RMgX) is prepared by heating or alkyl halide (R-X) with Mg in the presence of dry ether is called Grignard Reactions.

Grignard Reaction

Fitting Reactions: -The reactions in which di aryl is prepared by heating of two molecules of aryl halides with sodium in the presence or dry ether is called fitting reactions.

Fitting reactions

Wurtz Fitting Reactions: - The reactions in which allyl benzene is prepared by heating of alkyl halide and aryl halides with Na in the presence of dry ether is called Wurtz fitting reactions.

Wurtz reaction


Williamson's Synthesis: -The reactions in which ethers (-0-) are prepared by heating of alkyl halides with sodium alkoxide (Na-0-R) or, sodium phenoxide is called Williamson's synthesis.

Williamson's Synthesis

Kolbe's Electrolysis Reactions: - The electrolysis of Na/K salts of carboxylic acid in aqueous solution to give alkane, alkene and alkyne is called Kolbe' s electrolysis reactions.

Friedel Craft Alkylation: - he reactions in which alkyl benzene is prepared by heating of alkyl halides with benzene in the presence of anhydrous AlCl3 is called Friedel craft alkylation.

Friedel craft Alkylation


 

Friedel craft Acylation:  - The reactions in which aromatic ketones (R-CO-Ar) are prepared by heating of acid chloride(R-CoCl) or, anhydride with benzene in the presence of anhydrous AlCl3 is called Friedel Craft Acylation.

Fridel craft Acylation

Diazotization Reactions: - The reactions in which benzene diazonium chloride is prepared by heating of aniline, dilute HCl/ H2So4 and cold HNO2 at 0'c-5'c is called diazotization reactions.

Hoffmann's Bromide reactions: - The reactions in which P- amine is prepared by heating of amides (R-CoNH2), Br2 and KOH/NaOH solution is called Hoffmann's bromide reactions

Carbylamine Reactions: -The reactions in which alkyl isocyanide is prepared by heating of P- amine (R-NH2), chloroform and KOH solution is called carbylamine reactions.

Carbylamine reactions

Riemer- Tiemann Reactions: - The reactions in which hydroxy benzaldehyde ( salicyldehyde) is prepared by heating of phenol: CHCI3 and KOH solution at 340k is called Riemer Tiemann reaction.

Finkelstein Reactions: - The reactions in which chloroalkane or bromoalkene is treated with Nal dissolved in acetone is called Finkelstein reactions. 

Clemmensen Reduction: -The reactions in which aldehyde or ketone is reduced wit ZnHa/conc. HCI to form alkanes is called Clemmensen reduction.

Esterification Reactions: - The reactions in which esters is prepared by heating of carboxylic acid with an alcohol in the presence of conc. H2s04 is called esterification reactions.

esterification reaction

Cannizzaro's Reactions: - The reactions in which the aldehyde is treated with conc. NaOH to form sodium salt and an alcohol is called Cannizzaro's reactions. 

Elb's Reactions: - The reaction in which phenol is oxidised with K2S2O8 to form O/P dihydroxy benzene is called Elb's reactions.

Ullmann Reactions: - The reactions in which two molecules of iodo benzene is heated with Cu to form biphenyl is called Ullmann reactions. 

Étard's Reactions: - The reactions in which Toluene (methyl benzene) is oxidised with chromyl chloride in the presence of CCI4 or CS2 to form benzaldehyde is called Étard's reactions.

Etard's Reaction

Sandmeyer Reactions: - The conversion of benzene diazonium chloride into chlorobenzene, bromobenzene or cyanobenzene with CuCl/HCI, CuBr/HBr, CuCn/KCn is called Sandmeyer reactions.

Aldol Condensation Reactions: - The reactions in which aldehyde or ketones is heated with dil. NaOH to form B-hydroxy aldehyde or B- hydroxy Ketones is called aldol condensation reactions.

Markownikoffs Rule: - According to this rule, the negative part or a reagent (HX) will be attached to an alkene or alkyne with less numbers or hydrogen atoms is called Markownioff's rule.

Antimarkownikoff's rule: - According to this rule, the negative part of a reagent (HX) will be attached to an alkene or alkyne with higher number or hydrogen atom in the presence of peroxide is called Antimarkownikoff's rule. 

Tollen's Reagent: - The mixture of NH40H and AgNo3 is called tollens reagent.

Fehling Solution: - The mixture of Cuso4 and NaOH is called Fehling solutions.


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